Conformational design concepts for anions in ionic liquids
نویسندگان
چکیده
منابع مشابه
Ionic liquids with metal chelate anions.
A series of stable (air, water stable and with good thermal stability) and hydrophobic ionic liquids based upon metal chelate anions were synthesized, which were shown to be effective, mild, and easy to recycle catalysts at the same time stable solvents for the oxidation of cyclohexene.
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Ionic liquids containing the hexafluoroacetylacetonate anion are immiscible with water and they exhibit strong metal-complexing ability.
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Four paramagnetic ionic compounds have been prepared and their magnetic, structural and thermal properties have been investigated. The four compounds are methylbutylpyrrolidinium tetrachloroferrate(III) ([Pyrr(14)](+)/[FeCl(4)](-)), methyltributylammonium tetrachloroferrate(III) ([N(1444)](+)/[FeCl(4)](-)), butylmethylimidazolium tetrachloroferrate(III) ([bmim](+)/[FeCl(4)](-)) and tetrabutylam...
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Halogenated and alkoxylated closo-dodecaborates [B12X11OR](2-) (X = Cl, Br; R = propyl, octyl, dodecyl) have been synthesized by halogenation of the known [B12H11OH](2-) anion followed by alkylation in the superbasic medium DMSO/KOH. The obtained sodium salts were transformed by simple metathesis reactions in aqueous solution to the tetrabutylammonium ([NBu4](+)) and 1-hexyl-3-methylimidazolium...
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Nanoparticles assemblies of hundreds to thousands of atoms and a size in the range of 1-50 nm can be considered at first approximation as a state of matter intermediate between single atoms or molecules and bulk bodies. While the properties of atoms and molecules can be described via quantum mechanics, the properties of bulk bodies are described by solidstate physics. Using quantum chemical mod...
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ژورنال
عنوان ژورنال: Chemical Science
سال: 2020
ISSN: 2041-6520,2041-6539
DOI: 10.1039/d0sc01379j